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低温オーブントラッピングキャピラリーガスクロマトグラフィーによるクレゾール異性体およびフェノールの分析
http://hdl.handle.net/10271/1725
http://hdl.handle.net/10271/1725199878e4-8bb7-4def-ab42-7fd9c5ff7ab0
名前 / ファイル | ライセンス | アクション |
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FT-18-136.pdf (131.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-08-27 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 低温オーブントラッピングキャピラリーガスクロマトグラフィーによるクレゾール異性体およびフェノールの分析 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
その他のタイトル | ||||||
その他のタイトル | DETERMINATION OF CRESOL ISOMERS AND PHENOL BY CAPILLARY GAS CHROMATOGRAPHY WITH CRYOGENIC OVEN TRAPPING | |||||
言語 | en | |||||
著者 |
李, 暁鵬
× 李, 暁鵬× 熊澤, 武志× 近藤, 圭× 佐藤, 啓造× 鈴木, 修 |
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書誌情報 |
ja : 法中毒 en : Japanese journal of forensic toxicology 巻 18, 号 2, p. 136-137, 発行日 2000-05-15 |
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出版者 | ||||||
言語 | ja | |||||
出版者 | 日本法中毒学会 | |||||
権利 | ||||||
言語 | ja | |||||
権利情報 | Copyright 日本法中毒学会 | |||||
権利 | ||||||
言語 | ja | |||||
権利情報 | 本文データは日本法中毒学会の許諾のもと掲載しています。 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A simple method for determination of o-cresol, m-cresol, p-cresol and phenol from human body fluids by capillary gas chromatography (GC) has been developed using cryogenic oven trapping. After heating a whole blood or urine sample containing the four compounds and 2,4-dimethylphenol as internal standard in a 7.5 ml-vial at 100℃ for 10 min, 5 ml of headspace vapor was drawn into a gas tight syringe. All vapor was introduced through an injection port of a GC instrument in the splitless mode into an α-DEX 120 middle-bore capillary column at 0℃ of oven temperature for trapping the compounds; the oven temperature was programmed up to 170℃ for their detection by GC with flame ionization detection. The present conditions gave sharp peaks for the compounds, a good separation of each peak and low background impurities for whole blood and urine samples. The extraction efficiencies of the compounds were 0.25-0.68 % for whole blood and 0.51-1.14 % for urine. The calibration curves for all compounds showed good linearity in the range 1-10 μg/0.5 ml and the detection limits were 0.3-0.5μg/0.5 ml. | |||||
言語 | en | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09159606 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |