{"created":"2023-06-20T15:47:09.491329+00:00","id":1700,"links":{},"metadata":{"_buckets":{"deposit":"492f2187-e942-40c1-8447-7e1305ad4c7c"},"_deposit":{"created_by":4,"id":"1700","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"1700"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00001700","sets":["1:11"]},"author_link":["3952","3953","3954","3955","3956","3957","3958"],"item_3_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"水道水・尿・血漿中微量銅のESRによる迅速定量法","subitem_alternative_title_language":"ja"}]},"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001-09-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"242","bibliographicPageStart":"236","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"法中毒","bibliographic_titleLang":"ja"},{"bibliographic_title":"Japanese journal of forensic toxicology","bibliographic_titleLang":"en"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The ESR was applied to quantitation of Cu++ in running water, urine and plasma. Diethyldithiocarbamate (DDC) reacted with Cu++ in a wide pH range from 1 to 10. The Cu++-DDC complex could be extracted with many organic solvents at these pHs. Among organic solvents tested, 1-octanol was the most suitable solvent, which enabled condensation of Cu++ by 50 times with one extraction. By this method, we could measure Cu++ in 1.5 ml of either running water or urine and in 5μl of plasma within 5 min. Bilirubin and anticoagulants such as EDTA, oxalic acid, succinic acid and heparin did not inhibit the reaction of Cu++ with DDC. Signals of other transition metals were not observed in the ESR spectrum of Cu++, though most transition metals reacted with DDC. The Cu++-DDC complex in 1-octanol was quite stable and was not decomposed for 3 days under room light at room temperature. Data of Cu++ levels in actual samples were also presented.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本法中毒学会","subitem_publisher_language":"ja"}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright 日本法中毒学会","subitem_rights_language":"ja"},{"subitem_rights":"本文データは日本法中毒学会の許諾のもと掲載しています。","subitem_rights_language":"ja"}]},"item_3_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09159606","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Minakata, Kayoko"}],"nameIdentifiers":[{"nameIdentifier":"3952","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozawa, Hideki"}],"nameIdentifiers":[{"nameIdentifier":"3953","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Kanako"}],"nameIdentifiers":[{"nameIdentifier":"3954","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Osamu"}],"nameIdentifiers":[{"nameIdentifier":"3955","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kawai, Kaori"}],"nameIdentifiers":[{"nameIdentifier":"3956","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Horio, Fumihiko"}],"nameIdentifiers":[{"nameIdentifier":"3957","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Kanako"}],"nameIdentifiers":[{"nameIdentifier":"3958","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"FT-19-236.pdf","filesize":[{"value":"289.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"FT-19-236.pdf","url":"https://hama-med.repo.nii.ac.jp/record/1700/files/FT-19-236.pdf"},"version_id":"3a886830-7bc8-4c1d-8872-1b5a1cae9a26"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Copper","subitem_subject_scheme":"Other"},{"subitem_subject":"ESR","subitem_subject_scheme":"Other"},{"subitem_subject":"Diethyldithiocarbamate","subitem_subject_scheme":"Other"},{"subitem_subject":"Octanol","subitem_subject_scheme":"Other"},{"subitem_subject":"Urine","subitem_subject_scheme":"Other"},{"subitem_subject":"Plasma","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A RAPID AND SENSITIVE PROCEDURE FOR DETERMINATION OF COPPER IN RUNNING WATER, URINE AND PLASMA BY ESR","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A RAPID AND SENSITIVE PROCEDURE FOR DETERMINATION OF COPPER IN RUNNING WATER, URINE AND PLASMA BY ESR","subitem_title_language":"en"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-08-27"},"publish_date":"2013-08-27","publish_status":"0","recid":"1700","relation_version_is_last":true,"title":["A RAPID AND SENSITIVE PROCEDURE FOR DETERMINATION OF COPPER IN RUNNING WATER, URINE AND PLASMA BY ESR"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T04:00:32.706154+00:00"}