{"created":"2023-06-20T15:47:09.694159+00:00","id":1703,"links":{},"metadata":{"_buckets":{"deposit":"837f9a94-38bb-4d9c-9f16-f92ac8e3ae15"},"_deposit":{"created_by":4,"id":"1703","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"1703"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00001703","sets":["1:11"]},"author_link":["3971","3972","3973","3974","3975"],"item_3_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Sensitive quantification of manganese by use of ESR method","subitem_alternative_title_language":"en"}]},"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-05-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"197","bibliographicPageStart":"196","bibliographicVolumeNumber":"20","bibliographic_titles":[{"bibliographic_title":"法中毒","bibliographic_titleLang":"ja"},{"bibliographic_title":"Japanese journal of forensic toxicology","bibliographic_titleLang":"en"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A colorimetric method which is sensitive and specific to Mn has not been reported yet. A conventional flame atomic absorption method requires 1 g of liver containing 1ppm Mn, which is the highest concentration among soft tissues. Application of ESR method is examined in the present work because Mn(+2) is paramagnetic and can be measured by ESR method. Mn takes only +2 state in acid solution although it has several valence states from -2 to +7. In ESR spectrum Mn(+2) in acid solution shows characteristic 6 lines. The gvalue of the 3rd and 4th lines are 2.037 and 1.979, respectively, and the hyperfine splitting between them is 9.6 mT. Tissues were wet-ashed with conc nitric acid, and the diluted ashed solution was put into a quartz capillary and measured by an ESR spectrometer. In osteogenic disorder Shionogi rats intoxicated with paraquat, the Mn level was decreased to 0.6-fold of the control in liver and 0.7-fold in kidney, respectively. For the quantification, 1 mg of wet liver or kidney is enough,and the limit of detection is 60 pg of Mn. The ashed sample is stable for more than a year. Unlike the atomic absorption or emission method where the samples is burned out, the sample used in ESR method can be used for another purpose.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本法中毒学会","subitem_publisher_language":"ja"}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright 日本法中毒学会","subitem_rights_language":"ja"},{"subitem_rights":"本文データは日本法中毒学会の許諾のもと掲載しています。","subitem_rights_language":"ja"}]},"item_3_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09159606","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"南方, かよ子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"渡部, 加奈子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"野澤, 秀樹"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木, 修"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木, 加奈子"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"FT-20-196.pdf","filesize":[{"value":"102.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"FT-20-196.pdf","url":"https://hama-med.repo.nii.ac.jp/record/1703/files/FT-20-196.pdf"},"version_id":"dffdcba9-1207-452e-951f-5f55e68cc871"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"電子スピン共鳴を用いたマンガンの微量定量法","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"電子スピン共鳴を用いたマンガンの微量定量法","subitem_title_language":"ja"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-08-27"},"publish_date":"2013-08-27","publish_status":"0","recid":"1703","relation_version_is_last":true,"title":["電子スピン共鳴を用いたマンガンの微量定量法"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T04:00:39.285971+00:00"}