{"created":"2023-06-20T15:47:10.115807+00:00","id":1709,"links":{},"metadata":{"_buckets":{"deposit":"0cf44253-870c-43d9-ad90-b0098f43f9d8"},"_deposit":{"created_by":4,"id":"1709","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"1709"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00001709","sets":["1:11"]},"author_link":["4010","4011","4012","4013","4014"],"item_3_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Determination of nitrite by use of ESR method","subitem_alternative_title_language":"en"}]},"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-05-31","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"145","bibliographicPageStart":"144","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"法中毒","bibliographic_titleLang":"ja"},{"bibliographic_title":"Japanese journal of forensic toxicology","bibliographic_titleLang":"en"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A simple and sensitive method for the determination of nitrite has been developed. Nitrite can easily be reduced to NO radical by weak reductants such as ascorbic acid, I- and V3+ at room temperature. Some NO detection systems, already applied to the quantitation of nitrite, are chemiluminescence assay and ESR assay at 77 K after the trapping NO by hemoglobin. Our ESR method is based on the trapping NO by a metal-chelator complex consisting of ferrous ion(Fe2+) and diethyldithiocarbamic acid(DDC) in cycohexanol. The complex NO-Fe2+-(DDC)2 shows a characteristic three-line hyperfine structure(αN = 1.26 mT) with g value of 2.040 at room temperature. One sample can be quantitated within 5 min. When the sample tube was sealed from air with patty, the signal intensity remained constant for 30 days under room light at room temperature. By use of the present ESR method, NO at the concentration from 0.35 μM to 100 μM in 6 μｌ of cycohexanol is quantitated with the detection limit of 0.1 ng.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本法中毒学会","subitem_publisher_language":"ja"}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright 日本法中毒学会","subitem_rights_language":"ja"},{"subitem_rights":"本文データは日本法中毒学会の許諾のもと掲載しています。","subitem_rights_language":"ja"}]},"item_3_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09159606","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"南方, かよ子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"野澤, 秀樹"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"渡部, 加奈子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木, 修"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木, 加奈子"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"FT-21-144.pdf","filesize":[{"value":"112.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"FT-21-144.pdf","url":"https://hama-med.repo.nii.ac.jp/record/1709/files/FT-21-144.pdf"},"version_id":"88e9b107-f5ba-4168-987a-91033b18544e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"電子スピン共鳴法を用いた亜硫酸イオンの定量法","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"電子スピン共鳴法を用いた亜硫酸イオンの定量法","subitem_title_language":"ja"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-08-27"},"publish_date":"2013-08-27","publish_status":"0","recid":"1709","relation_version_is_last":true,"title":["電子スピン共鳴法を用いた亜硫酸イオンの定量法"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T04:00:53.874373+00:00"}