{"created":"2023-06-20T15:47:10.466666+00:00","id":1714,"links":{},"metadata":{"_buckets":{"deposit":"65318dbb-58a9-4c15-9c48-d47562c1d04e"},"_deposit":{"created_by":4,"id":"1714","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"1714"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00001714","sets":["1:11"]},"author_link":["4045","4046","4047","4048"],"item_3_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Determination of azide by use of ESR method","subitem_alternative_title_language":"en"}]},"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-04-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"135","bibliographicPageStart":"134","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"法中毒","bibliographic_titleLang":"ja"},{"bibliographic_title":"Japanese journal of forensic toxicology","bibliographic_titleLang":"en"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A simple and sensitive method for the determination of sodium azide has been developed. In the presence of pyridine (Py), Cu reacts with azide ion (N3-) most preferentially among common metals found in biological fluids. The procedure is based on the formation of paramagnetic complex CU(N3)2(Py)x in chloroform and its detection by electron spin resonance (ESR) method. The complex shows a characteristic four-line hyperfine structure (aN = 5.24mT) with g value of 2.109 at room temperature. Interference from coexisting large amount of cations, anions and reductants can be eliminated by adding either CuSO4 or oxidants. By use of the present ESR method, N3- at the concentration from 50 μM to 10 mM in 20 μL solution is quantitated with the detection limit of 40 ng. One sample can be quantitated within 5 min.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本法中毒学会","subitem_publisher_language":"ja"}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright 日本法中毒学会","subitem_rights_language":"ja"},{"subitem_rights":"本文データは日本法中毒学会の許諾のもと掲載しています。","subitem_rights_language":"ja"}]},"item_3_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09159606","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"南方, かよ子"}],"nameIdentifiers":[{"nameIdentifier":"4045","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"野澤, 秀樹"}],"nameIdentifiers":[{"nameIdentifier":"4046","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"渡部, 加奈子"}],"nameIdentifiers":[{"nameIdentifier":"4047","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鈴木, 修"}],"nameIdentifiers":[{"nameIdentifier":"4048","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"FT-22-134.pdf","filesize":[{"value":"118.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"FT-22-134.pdf","url":"https://hama-med.repo.nii.ac.jp/record/1714/files/FT-22-134.pdf"},"version_id":"9518d067-4b88-4432-aa0f-0a70cdc34d15"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"電子スピン共鳴を用いたアザイドの迅速定量法","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"電子スピン共鳴を用いたアザイドの迅速定量法","subitem_title_language":"ja"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-08-27"},"publish_date":"2013-08-27","publish_status":"0","recid":"1714","relation_version_is_last":true,"title":["電子スピン共鳴を用いたアザイドの迅速定量法"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T04:01:06.031555+00:00"}