{"created":"2023-06-20T15:47:10.707287+00:00","id":1719,"links":{},"metadata":{"_buckets":{"deposit":"02d4776b-290c-4aca-bcfd-63f20e241440"},"_deposit":{"created_by":4,"id":"1719","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"1719"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00001719","sets":["1:11"]},"author_link":["4076","4077","4078","4079"],"item_3_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"電子スピン共鳴法を用いたチオシアン酸イオンの迅速定量","subitem_alternative_title_language":"ja"}]},"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-01-31","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"44","bibliographicPageStart":"41","bibliographicVolumeNumber":"23","bibliographic_titles":[{"bibliographic_title":"法中毒","bibliographic_titleLang":"ja"},{"bibliographic_title":"Japanese journal of forensic toxicology","bibliographic_titleLang":"en"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A simple and sensitive method has been developed for determination of thiocyanate ion (SCN-), the main metabolite of cyanide, in biological fluids and beverages. The procedure was based on the formation of a paramagnetic complex Cu(SCN）2(4-methylpyridine）2 in benzene, followed by its detection by electron spin resonance (ESR). The complex showed a characteristic four-peak hyperfine structure with a g-value of 2.132 at room temperature. By the present method, SCN- at concentrations from 5 μM to 2 mM in 500 μl solution could be determined. The recoveries were more than 95% for SCN- added to blood, plasma, urine, milk and beverages at 200 μM. Several anions and cations in biological fluids did not interfere with the formation of the complex in the presence of large amounts of Cu2+. Our method is recommendable, because it takes only less than 10 min to determine SCN- and the produced complex is quite stable.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本法中毒学会","subitem_publisher_language":"ja"}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright 日本法中毒学会","subitem_rights_language":"ja"},{"subitem_rights":"本文データは日本法中毒学会の許諾のもと掲載しています。","subitem_rights_language":"ja"}]},"item_3_source_id_19":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09159606","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Minakata, Kayoko"}],"nameIdentifiers":[{"nameIdentifier":"4076","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozawa, Hideki"}],"nameIdentifiers":[{"nameIdentifier":"4077","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Kanako"}],"nameIdentifiers":[{"nameIdentifier":"4078","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Osamu"}],"nameIdentifiers":[{"nameIdentifier":"4079","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"FT-23-41.pdf","filesize":[{"value":"345.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"FT-23-41.pdf","url":"https://hama-med.repo.nii.ac.jp/record/1719/files/FT-23-41.pdf"},"version_id":"ecbc066c-e81a-497b-b321-fbe53c99fc35"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Thiocyanate","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyanide metabolite","subitem_subject_scheme":"Other"},{"subitem_subject":"Electron spin resonance","subitem_subject_scheme":"Other"},{"subitem_subject":"Copper","subitem_subject_scheme":"Other"},{"subitem_subject":"Blood","subitem_subject_scheme":"Other"},{"subitem_subject":"Urine","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"RAPID DETERMINATION OF THIOCYANATE IN BIOLOGICAL FLUIDS BY USE OF ELECTRON SPIN RESONANCE","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"RAPID DETERMINATION OF THIOCYANATE IN BIOLOGICAL FLUIDS BY USE OF ELECTRON SPIN RESONANCE","subitem_title_language":"en"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-08-27"},"publish_date":"2013-08-27","publish_status":"0","recid":"1719","relation_version_is_last":true,"title":["RAPID DETERMINATION OF THIOCYANATE IN BIOLOGICAL FLUIDS BY USE OF ELECTRON SPIN RESONANCE"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T04:01:20.133245+00:00"}