{"created":"2023-06-20T15:48:15.199401+00:00","id":2771,"links":{},"metadata":{"_buckets":{"deposit":"61a1a4c4-a9d8-4ce0-9f9f-c380ef8747b8"},"_deposit":{"created_by":4,"id":"2771","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"2771"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00002771","sets":["1:11"]},"author_link":[],"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"155","bibliographicPageStart":"149","bibliographicVolumeNumber":"30","bibliographic_titles":[{"bibliographic_title":"Forensic Toxicology"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A rapid and sensitive mass spectrometric method was developed for the simultaneous determination of coinage metals such as copper (Cu), silver (Ag) and gold (Au). The metals in a wet ashed tissue solution were complexed with diethyldithiocarbamate (DDC; C4H10NCS2) and were extracted together with isoamyl alcohol. After the acidification of the extract with oxalic acid, metals were quantified using their product ions, Cu(DDCH)+, Ag(DDCH) + and Au(DDCH)+ that derived from the precursor ions Cu(DDC)2+, Ag(DDC)2 + and Au(DDC)2+, respectively, by electrospray ionization tandem mass spectrometry. The limits of detection were 0.6, 0.3 and 1 μgl?1 for Cu, Ag and Au and the quantification ranges were 2 ? 100, 1 ? 100 and 3 ? 100 μgl?1 for Cu, Ag and Au, respectively. Cu levels in spontaneously hypertensive osteogenic disorder rats at 6 weeks old and at 30 weeks old were found to be 1.8 times and 5.1 times those of the normotensive osteogenic disorder rats, respectively, when using wet-ashed kidney solutions diluted to 1,000 fold.","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer Japan"}]},"item_3_relation_28":{"attribute_name":"出版社DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1007/s11419-012-0134-9","subitem_relation_type_select":"DOI"}}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"The final publication is available at Springer via http://dx.doi.org/10.1007/s11419-012-0134-9."}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Minakata, Kayoko"}]},{"creatorNames":[{"creatorName":"Yamagishi, Itaru"}]},{"creatorNames":[{"creatorName":"Nozawa, Hideki"}]},{"creatorNames":[{"creatorName":"Gonmori, Kunio"}]},{"creatorNames":[{"creatorName":"Hasegawa, Koutaro"}]},{"creatorNames":[{"creatorName":"Suzuki, Masako"}]},{"creatorNames":[{"creatorName":"Horio, Fumihiko"}]},{"creatorNames":[{"creatorName":"Watanabe, Kanako"}]},{"creatorNames":[{"creatorName":"Suzuki, Osamu"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"ft-30-149.pdf","filesize":[{"value":"7.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ft-30-149.pdf","url":"https://hama-med.repo.nii.ac.jp/record/2771/files/ft-30-149.pdf"},"version_id":"5343b2c9-5858-49a6-bec2-b368b3ca8665"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Copper","subitem_subject_scheme":"Other"},{"subitem_subject":"Silver","subitem_subject_scheme":"Other"},{"subitem_subject":"Gold","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrospray ionization","subitem_subject_scheme":"Other"},{"subitem_subject":"Tandem mass spectrometry","subitem_subject_scheme":"Other"},{"subitem_subject":"Diethyldithiocarbamate","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Simultaneous determination of coinage metals, copper, silver and gold in tissues using electrospray ionization tandem mass spectrometry","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Simultaneous determination of coinage metals, copper, silver and gold in tissues using electrospray ionization tandem mass spectrometry","subitem_title_language":"en"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2015-11-20"},"publish_date":"2015-11-20","publish_status":"0","recid":"2771","relation_version_is_last":true,"title":["Simultaneous determination of coinage metals, copper, silver and gold in tissues using electrospray ionization tandem mass spectrometry"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T05:06:43.454980+00:00"}