{"created":"2023-06-20T15:46:06.962734+00:00","id":604,"links":{},"metadata":{"_buckets":{"deposit":"2c84269b-48fe-4ff4-80b7-d4bd5566391d"},"_deposit":{"created_by":4,"id":"604","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"604"},"status":"published"},"_oai":{"id":"oai:hama-med.repo.nii.ac.jp:00000604","sets":["1:11"]},"author_link":["1869","1870","1871","1872","1873"],"item_3_alternative_title_1":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Determination of urinary uranium by solid fluorometry using a flying spot scanner"}]},"item_3_biblio_info_5":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1991-10-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"T173","bibliographicPageStart":"T171","bibliographicVolumeNumber":"40","bibliographic_titles":[{"bibliographic_title":"分析化学"}]}]},"item_3_description_9":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"従来のベレットを用いる固体蛍光光度法に代わるものとして著者らが既に確立した蛍光分析法を応用して, 酢酸ウラニルとしてウラン(VI)を静脈注射投与することにより急性じん不全を発症させたウサギの尿ウランの定量法を開発した.ウサギの尿を湿式分解した後, 酸化トリオクチルホスフィン-ベンゼン溶液を用いてウランを抽出し, その抽出液の一部をTLC板上に滴下して, そのスポットをフライングスポットスキャナにより蛍光分析した.本法は, 回収率95.4%, 標準偏差率5.9%でウサギの尿中の微量のウランを定量することができる.又, 従来の蛍光光度法と比較して分析操作が簡便なので単位時間当たりより多くの試料を分析することが可能である.  Solid fluorometry using a flying spot scanner is applied to the determination of urinary uranium of a rabbit which developed acute renal failure following intravenous administration of uranium as uranyl acetate. After decomposing a rabbit urinary sample |U (VI) 0.4μg| using conc. HNO_3 and conc. HClO_4,10 ml of the solution containing uranium (VI) adjusted to pH 3.7〜4.0 are shaken vigorously for about 30 min with 1 ml of 4×10^<-2> mol/l trioctylphosphine oxide-benzene solution and 1 ml of 2×10^<-2> mol/l benzoic acidbenzene solution in a 50 ml separatory funnel. A spot (0.5〜5μl) of the extract is dropped onto a TLC plate (10×10 cm) of Silica Gel-60 previously dried at 110℃ for 1 h. After drying it at 150℃ for 1 h and cooling, the fluorescence intensity of the spot (6 mm dia) is then measured by a flying spot scanner equipped with a xenon lamp at fluorescence excitation of 245 nm and fluorescence emission of 498 nm (filter type). Using this method, trace amounts of uranium in rabbit urine samples could be determined, with a recovery rate of 95.4% and a standard deviation rate of 5.9%.","subitem_description_type":"Abstract"}]},"item_3_publisher_6":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_3_relation_22":{"attribute_name":"NII論文ID","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"110002906208","subitem_relation_type_select":"NAID"}}]},"item_3_rights_7":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"日本分析化学会"},{"subitem_rights":"本文データは学協会の許諾に基づきCiNiiから複製したものである"}]},"item_3_version_type_32":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"一瀬, 典夫"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"足立, 恭子"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"山田, 雅仁"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"菱田, 明"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"本田, 西男"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-27"}],"displaytype":"detail","filename":"110002906208.pdf","filesize":[{"value":"247.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"110002906208.pdf","url":"https://hama-med.repo.nii.ac.jp/record/604/files/110002906208.pdf"},"version_id":"d748900b-9831-4b6b-a8d9-37fe949604d1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"fluorometric analysis of uranium","subitem_subject_scheme":"Other"},{"subitem_subject":"flying spot scanner","subitem_subject_scheme":"Other"},{"subitem_subject":"urinary uranium","subitem_subject_scheme":"Other"},{"subitem_subject":"trioctylphosphine oxide-benzene extraction","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"薄層クロマトグラフスキャナを用いる固体蛍光分析法による尿中ウランの定量","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"薄層クロマトグラフスキャナを用いる固体蛍光分析法による尿中ウランの定量","subitem_title_language":"ja"}]},"item_type_id":"3","owner":"4","path":["11"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-08-27"},"publish_date":"2013-08-27","publish_status":"0","recid":"604","relation_version_is_last":true,"title":["薄層クロマトグラフスキャナを用いる固体蛍光分析法による尿中ウランの定量"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-08-02T05:50:31.004398+00:00"}