| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2013-08-27 |
| タイトル |
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タイトル |
An Attempt Directed toward Enhanced Shape Selectivity in Reversed-Phase Liquid Chromatography: Preparation of the Dodecylaminated β-Cyclodextrin-Bonded Phase |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
Fujimoto, Chuzo
Maekawa, Akira
Murao, Yumiko
Jinno, Kiyokatsu
Takeichi, Tsutomu
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| 書誌情報 |
Analytical Sciences
巻 18,
号 1,
p. 65,
発行日 2002-01-10
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| 出版者 |
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出版者 |
日本分析化学会 Japan Society for Analytical Chemistry |
| 権利 |
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権利情報 |
© 2009 The Japan Society for Analytical Chemistry |
| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
With the aim of preparing a stationary phase with a high shape-recognition ability for liquid chromatography, a new bonded phase was synthesized by coupling multiply dodecylamino-substituted β-cyclodextrin (β-CD) to 3-glycidoxypropyl-derivatized silica gel. The stationary phase prepared in this way was expected to have increased shape selectivity compared with that of conventional reversed-phase materials, due to solute interactions with the alkyl chain piles built up on the β-CDs bonded to silica. The separation characteristics of the bonded phase were investigated using polycyclic aromatic hydrocarbons (PAHs) with different molecular shapes and compared with those of monomeric ODS and native β-cyclodextrin-bonded phases. The newly developed stationary phase was found to be highly selective for PAHs. |
| ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
09106340 |
| EISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
13482246 |
| 出版社DOI |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
DOI |
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関連識別子 |
10.2116/analsci.18.65 |
| 著者版フラグ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
AnalSci-18_1-65.pdf (116.7 kB)
