| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2013-08-27 |
| タイトル |
|
|
タイトル |
SENSITIVE DETERMINATION OF TRICHLOROETHYLENE IN BLOOD AND URINE BY CAPILLARY GAS CHROMATOGRAPHY WITH CRYOGENIC TRAPPING |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題 |
Trichloroethylene |
| キーワード |
|
|
主題 |
Tetrachloroethylene |
| キーワード |
|
|
主題 |
Gas chromatography |
| キーワード |
|
|
主題 |
Cryogenic trapping |
| キーワード |
|
|
主題 |
Headspace method |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| その他のタイトル |
|
|
その他のタイトル |
低温トラッピングキャピラリーガスクロマトグラフィーによる血中尿中トリクロロエチレンの高感度定量 |
| 著者 |
Watanabe, Kanako
Seno, Hiroshi
Ishii, Akira
Kumazawa, Takeshi
Hattori, Hideki
Suzuki, Osamu
|
| 書誌情報 |
ja : 法中毒
en : Japanese journal of forensic toxicology
巻 15,
号 3,
p. 211-216,
発行日 1997-09-16
|
| 出版者 |
|
|
出版者 |
日本法中毒学会 |
|
言語 |
ja |
| 権利 |
|
|
権利情報 |
Copyright 日本法中毒学会 |
| 権利 |
|
|
権利情報 |
本文データは日本法中毒学会の許諾のもと掲載しています。 |
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
A new and sensitive method for measurements of trichloroethylene in blood and urine by capillary gas chromatography (GC) with cryogenic trapping is presented. After heating a body fluid samples (1ml) containing trichloroethylene and tetrachloroethylene (internal standard. IS) in a 7.0-ml vial at 55℃ for 20 min, 5 ml of the headspace vapor was drawn into a glass syringe. All vapor was introduced into an Rtx-Volatiles middle-bore capillary column in the splitless mode at 0 ℃ of oven temperature to trap the entire analytes. and the oven temperature was programmed up to 270℃. The present conditions gave sharp peaks for both trichloroethylene and tetrachloroethylene (IS), and low background noises for whole blood and urine samples. As much as 75.0 and 63.1 % of trichloroethylene and IS. respectively, which had been added to whole blood in a vial, could be introduced into the GC column. The calibration curves showed linearity in the range of 0.5-5.0μg/ml for both whole blood and urine. The detection limit was as low as about 3 ng/ml of whole blood. |
| ISSN |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
09159606 |
| 著者版フラグ |
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|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
FT-15-211.pdf (235.0 kB)
