WEKO3
アイテム
{"_buckets": {"deposit": "4be10f07-1360-4b92-9a17-1c0669f3c226"}, "_deposit": {"created_by": 4, "id": "1883", "owners": [4], "pid": {"revision_id": 0, "type": "depid", "value": "1883"}, "status": "published"}, "_oai": {"id": "oai:hama-med.repo.nii.ac.jp:00001883", "sets": ["11"]}, "author_link": ["4845", "4846", "4847", "4848", "4849"], "item_3_biblio_info_5": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2009-09-28", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "84", "bibliographicPageStart": "81", "bibliographicVolumeNumber": "651", "bibliographic_titles": [{"bibliographic_title": "Analytica Chimica Acta", "bibliographic_titleLang": "en"}]}]}, "item_3_description_30": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_3_description_9": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A rapid and sensitive electrospray ionization tandem mass spectrometric (ESI-MS-MS) procedure was developed for the determination of cyanide (CN-). CN- in biological fluids was reacted with NaAuCl4 to produce dicyanogold, Au(CN)2- which was extracted with methyl isobutyl ketone (MIBK). One μL of the extract was injected directly into an ESI-MS-MS instrument. Quantification of CN-was performed by selected reaction monitoring of the product ion CN- at m/z 26 that derived from precursor ion Au(CN)2- at m/z 249. CN- could be measured in the quantification range of 10-7 to 5×10-5 M with the limit of detection at 4×10-8 M using 10 μL of urine within 10 min. A victim’s urine and gastric content were diluted with water to 4-fold and 500-fold and measured, respectively.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_3_publisher_6": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier", "subitem_publisher_language": "en"}]}, "item_3_relation_28": {"attribute_name": "出版社DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.aca.2009.08.001", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_7": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright 2009 Elsevier B.V.", "subitem_rights_language": "en"}]}, "item_3_select_2": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"subitem_select_item": "Journal Article", "subitem_select_language": "en"}]}, "item_3_source_id_19": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "00032670", "subitem_source_identifier_type": "ISSN"}]}, "item_3_version_type_32": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Minakata, Kayoko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "4845", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nozawa, Hideki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "4846", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Gonmori, Kunio", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "4847", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzuki, Masako", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "4848", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzuki, Osamu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "4849", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-08-27"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACA-651-81.pdf", "filesize": [{"value": "254.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 254900.0, "url": {"label": "ACA-651-81.pdf", "url": "https://hama-med.repo.nii.ac.jp/record/1883/files/ACA-651-81.pdf"}, "version_id": "048f027b-9434-4fbb-b59a-bc1cd0a1b7d5"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Cyanide", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Gold", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electrospray ionization", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Tandem mass spectrometry", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Urine", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Determination of cyanide, in urine and gastric content, by electrospray ionization tandem mass spectrometry after direct flow injection of dicyanogold", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Determination of cyanide, in urine and gastric content, by electrospray ionization tandem mass spectrometry after direct flow injection of dicyanogold", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "4", "path": ["11"], "permalink_uri": "http://hdl.handle.net/10271/1920", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2013-08-27"}, "publish_date": "2013-08-27", "publish_status": "0", "recid": "1883", "relation": {}, "relation_version_is_last": true, "title": ["Determination of cyanide, in urine and gastric content, by electrospray ionization tandem mass spectrometry after direct flow injection of dicyanogold"], "weko_shared_id": -1}
Determination of cyanide, in urine and gastric content, by electrospray ionization tandem mass spectrometry after direct flow injection of dicyanogold
http://hdl.handle.net/10271/1920
http://hdl.handle.net/10271/1920170feb01-f667-4867-9733-b409bdd02daf
名前 / ファイル | ライセンス | アクション |
---|---|---|
ACA-651-81.pdf (254.9 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2013-08-27 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Determination of cyanide, in urine and gastric content, by electrospray ionization tandem mass spectrometry after direct flow injection of dicyanogold | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Cyanide | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Gold | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Electrospray ionization | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Tandem mass spectrometry | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Urine | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Minakata, Kayoko
× Minakata, Kayoko× Nozawa, Hideki× Gonmori, Kunio× Suzuki, Masako× Suzuki, Osamu |
|||||
書誌情報 |
en : Analytica Chimica Acta 巻 651, 号 1, p. 81-84, 発行日 2009-09-28 |
|||||
出版者 | ||||||
言語 | en | |||||
出版者 | Elsevier | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | Copyright 2009 Elsevier B.V. | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A rapid and sensitive electrospray ionization tandem mass spectrometric (ESI-MS-MS) procedure was developed for the determination of cyanide (CN-). CN- in biological fluids was reacted with NaAuCl4 to produce dicyanogold, Au(CN)2- which was extracted with methyl isobutyl ketone (MIBK). One μL of the extract was injected directly into an ESI-MS-MS instrument. Quantification of CN-was performed by selected reaction monitoring of the product ion CN- at m/z 26 that derived from precursor ion Au(CN)2- at m/z 249. CN- could be measured in the quantification range of 10-7 to 5×10-5 M with the limit of detection at 4×10-8 M using 10 μL of urine within 10 min. A victim’s urine and gastric content were diluted with water to 4-fold and 500-fold and measured, respectively. | |||||
言語 | en | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00032670 | |||||
出版社DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.aca.2009.08.001 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |